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Pharmaceutical Book from C.H.I.P.S.

Micellar Catalysis
by Mohammad Niyaz Khan

Micellar Catalysis is an in-depth examination of how micelles affect reaction mechanisms and reaction rates in organic and inorganic reactions.

Features:

  • Provides detailed mechanisms for all types of micelle-mediated reactions
  • Explains how physicochemical properties and intermolecular interactions of micelles influence reaction mechanisms
  • Includes dispersed medium (DM) model of micellar solution
  • Analyzes how micelles affect reaction rates and rate constants in unimolecular, solvolytic, and bimolecular organic reactions
  • Covers the effects of mixed aqueous-organic solvents on the micellar binding constants of solubilizates
  • Illustrates how industrial processes can benefit from micellar-mediated chemical reactions

Contents

Micelles

  • Normal Micelles
  • Hemimicelles
  • Reversed Micelle

Catalysis in Chemical Reactions: General Theory of Catlysis

  • Mechanistic Change in Catalyzed Reactions
  • Proximity and Shielding Effects of Catalyst
  • Classification of Catalysis

General Mechanisms of Micellar Catlysis

  • Preequilibrium Kinetic Model of the Micelle
  • Pseudophase Model of the Micelle
  • Berezin's Pseudophase Model
  • The Multiple Micellar Pseudophase Model
  • Other Micellar Kinetic Models
  • Dispersed Medium Model of Micellar Solution

Normal Micelle: Effects on Reaction Rates

  • Unimolecular and Solvolytic Reactions
  • Bimolecular Reactions
  • Intramolecular Reactions
  • Effects of Mixed Aqueous-Organic Solvents on Micellar Binding Constants (KS) of Solubilizates
  • Micelle as Modifier of Reaction Rate

Mixed Normal Micelles: Effects on Reaction Rates

  • Unimolecular and Solvolytic Reactions
  • Bimolecular Reactions

Metallomicelles: Effects on Reaction Rates

  • Nonfunctional Metallomicelles
  • Induced Functional Metallomicelles

Chemical Kinetics and Kinetic Parameters

  • Fundamentals of Chemical Kinetics
  • Empirical Kinetic Equations
  • Reaction Mechanism, Theoretical Rate Law, and Theoretical Kinetic Equations
  • Reliability of Derived or Calculated Kinetic Parameters

Index

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Micellar Catalysis
by Mohammad Niyaz Khan
2006 482 pages $188.95 + shipping
Texas residents please add 6.75 % sales tax

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