Catalysts for Fine Chemical Synthesis: Vol. 2 contains tested and validated procedures and provides a unique resource for chemists who work in organic chemistry.
Catalysts for Fine Chemical Synthesis: Vol. 2 presents a survey of recent developments in catalysis by polyoxometalates for fine chemicals synthesis. One chapter concentrates on the practical preparation of specific acid and oxidation catalysts. Other chapters describe in detail the use of homogeneous and heterogeneous synthesis.
Contents
- Introduction
- Scope and definitions
- Nomenclature
- Historical background
- Introduction to catalysis by polyoxometalates
- Properties of Polyoxometalates
- Structures of polyoxometalates
- Crystal structure of heteropoly compounds
- Thermal stability
- Solubility
- Formation and state in solution
- Acid properties
- Redox properties
- Synthesis of Polyoxometalates
- General methods of synthesis
- Keggin polyoxometalates
- Wells-Dawson polyoxometalates
- Sandwich-type polyoxometalates
- Peroxo polyoxometalates
- Polyoxometalate catalysts
- Acid Catalysis by Heteropoly Compounds
- General overview
- Homogeneous acid catalysis
- Acid-catalysed reactions in biphasic liquid-liquid systems
- Heterogeneous acid catalysts
- Deactivation and regeneration of solid heteropoly acid catalysts
- Polyoxometalates as Catalysts for Selective Oxidation
- Liquid-phase oxidation
- Gas-phase oxidation
- Miscellaneous Catalytic Applications of Polyoxometalates
- Hydrogenation, carbonylation and related reactions
- Polyanion-stabilised clusters
- Polyoxometalates as catalyst precursors
- Catalysis by Polyoxometalates in Industry
- Acid catalysis
- Selective oxidation
- Other Applications of Polyoxometalates
- Analytical chemistry
- Separation
- Corrosion-resistant coatings
- Polyoxometalates as additives to inorganic and organic matrices
- Membranes
- Polyoxometalates in medicine: antiviral and antitumoral activity
Index
See also:
Volume 1: Hydrolysis, Oxidation and Reduction
Volume 3: Metal Catalysed Carbon-Carbon Bond-Forming Reactions
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