Handbook of Basic Tables for Chemical Analysis
Second Edition
by Thomas J. Bruno
and Paris D.N. Svoronos
- Compiles a huge array of useful and important data into a series of tables that provide important data in a single, convenient source for use in the analytical laboratory
- Provides a self-contained resource that covers not only how to carry out a lab procedure but how to carry it out safely
- Includes valuable information on chemical hazards, electrical hazards, and suggests how to select laboratory gloves, apparel, and respirators
- Lists chemical incompatibilities of various compounds
- Covers both "instrumental" methods and "wet" chemical techniques
The Handbook of Basic Tables for Chemical Analysis, Second Edition is your one-stop source for the information needed to design chemical analyses.
New to this edition:
- New chapters on solutions, electroanalytical methods, electrophoresis, and laboratory safety
- An expanded section on gas chromatography that includes data on compounds that attack common detectors
- New information on detector optimization
- An updated section on high performance liquid chromatography that provides the most recent chiral stationary phases, detector information, and revised solvent tables
- Updated information on the most useful "wet" chemistry methods
- Enlarged section of Miscellaneous Tables
Going far beyond the landmark first edition in terms of scope and applications, the second edition provides current and updated data culled from a wide range of resources and consolidated into a concise yet easy-to-use format. The book's laser-like focus on core information gives you the knowledge you need when you need it - at the decision point.
Contents
- Gas Chromatography
- Carrier Gas Properties
- Carrier Gas Viscosity
- Gas Chromatographic Support Materials for Packed Columns
- Mesh Sizes and Particle Diameters
- Packed Column Support Modifiers
- Properties of Chromatographic Column Materials
- Properties of Some Liquid Phases for Packed Columns
- Stationary Phases for Packed Column Gas Chromatography
- Adsorbents for Gas-Solid Chromatography
- Porous Polymer Phases
- Silicone Liquid Phases
- Mesogenic Stationary Phases
- Trapping Sorbents
- Sorbents for the Separation of Volatile Inorganic Species
- Activated Carbon as a Trapping Sorbent for Trace Metals
- Reagent Impregnated Resins as Trapping Sorbents for Trace Minerals
- Reagent Impregnated Foams as Trapping Sorbents for Inorganic Species
- Chelating Agents for the Analysis of Inorganics by Gas Chromatography
- Bonded Phase Modified Silica Substrates for Solid Phase Extraction
- Solid Phase Microextraction Sorbents
- Extraction Capability of Solid Phase Microextraction Sorbents
- Salting Out Reagents for Headspace Analysis
- Partition Coefficients of Common Fluids in Air-Water Systems
- Vapor Pressure and Density of Saturated Water Vapor
- Derivatizing Reagents for Gas Chromatography
- Detectors for Gas Chromatography
- Recommended Operating Ranges for Hot Wire Thermal Conductivity Detectors
- Chemical Compatibility of Thermal Conductivity Detector Wires
- Data for the Operation of Gas Density Detectors
- Phase Ratio for Capillary Columns.
- Martin-James Compressibility Factor and Giddings Plate Height Correction Factor
- Cryogens for Subambient Temperature Gas Chromatography
- High Performance Liquid Chromatography
- Modes of Liquid Chromatography
- Solvents for Liquid Chromatography
- Instability of HPLC Solvents
- Ultraviolet Absorbance of Reverse Phase Mobile Phases
- Ultraviolet Absorbance of Normal Phase Mobile Phases
- Some Useful Ion Pairing Agents
- Materials Compatible with and Resistant to 72 Percent Perchloric Acid
- More Common HPLC Column Packings
- Eluotropic Values of Solvents on Octadecylsilane
- Mesh Size Relationships
- Efficiency of HPLC Columns
- Column Failure Parameters
- Specialized Stationary Phases for Liquid Chromatography
- Chiral Stationary Phases for Liquid Chromatography
- Detectors for Liquid Chromatography
- Ultraviolet Detection of Chromophoric Groups
- Derivatizing Reagents for HPLC
- Thin Layer Chromatography
- Strength of Common TLC Solvents
- Modification of the Activity of Alumina by Addition of Water
- Stationary and Mobile Phases
- Typical Stationary and Mobile Phase Systems Used in the Separation of Various Inorganic Ions
- Spray Reagents in Thin Layer Chromatography
- Protocol for Reagent Preparation
- Supercritical Fluid Extraction and Chromatography
- Some Useful Fluids for Supercritical Fluid Extraction and Chromatography
- P-r-T Table for Carbon Dioxide
- Solubility parameters of the Most Common Fluids for Supercritical Fluid Extraction and Chromatography
- Instability of Modifiers used with Supercritical Fluids
- Electrophoresis
- Separation Ranges of Polyacrylamide Gels
- Preparation of Polyacrylamide Gels
- Buffer Mixtures Commonly Used for Polyacrylamide Gel Electrophoresis
- Proteins for Internal Standardization of Polyacrylamide Gel Electrophoresis
- Chromogenic Stains for Gels
- Fluorescent Stains for Gels
- Electroanalytical Methods
- Detection Limits for Various Electrochemical Techniques
- Values of (2.3026 RT/F) at Different Temperatures
- Potential of Zero Charge for Various Electrode Materials in Aqueous Solutions at Room Temperature
- Variation of Reference Electrode Potentials with Temperature
- pH Values of Standard Solutions used in the Calibration of Gas Electrodes
- Temperature vs. pH Correlation of Standard Solutions Used for the Calibration of Electrodes
- Solid Membrane Electrodes
- Liquid Membrane Electrodes
- Standard Reduction Electrode Potentials for Inorganic Systems in Aqueous Solutions at 25oC
- Standard Reduction Electrode Potentials for Inorganic Systems in Non-Aqueous Solutions at 25oC
- Standard Redox Potentials for Some Biological Half-Reactions
- Standard E.M.F. Values for the Cell H2 / HCl / AgCl, Ag in Various Solvents at Different Temperatures
- Temperature Dependence of the Standard Potential of the Silver Chloride Electrode
- Standard Electrode Potentials of Electrodes of the First Kind
- Standard Electrode Potentials of Electrodes of the Second Kind
- Polarographic Half-Wave Potentials (E½ ) of Inorganic Cations
- Polarographic E½ Ranges (in V vs. SCE) for the Reduction of Benzene Derivatives
- Vapor Pressure of Mercury
- Organic Functional Group Analysis of Non-Polarographic Active Groups
- Coulometric Titrations
- Ultraviolet Spectrophotometry
- Solvents for Ultraviolet Spectrophotometry
- Ultraviolet Spectra of Common Liquids
- Transmittance-Absorbance Conversion
- Correlation Table of Ultraviolet Active Functionalities
- Woodward's Rules for Bathochromic Shifts
- Infrared Spectrophotometry
- Infrared Optics Materials
- Internal Reflectance Element Characteristics
- Water Solubility of Infrared Optics Materials
- Wavelength-Wavenumber Conversion Table
- Useful Solvents for Infrared Spectrophotometry
- Polystyrene Wavenumber Calibration
- Infrared Absorption Correlation Charts
- Aromatic Substitution Bands
- Carbonyl Infrared Absorptions
- Infrared Absorptions of Major Chemical Families
- Common Spurious Infrared Absorption Bands
- Nuclear Magnetic Resonance Spectroscopy
- Properties of Important NMR Nuclei
- Gyromagnetic Ratio of Some Important Nuclei
- Classification of Important Quadrupolar Nuclei According to Natural Abundance and Magnetic Strength
- Chemical Shift Ranges of Some Nuclei
- Reference Standards for Selected Nuclei
- 1H and 13C Chemical Shifts of Useful Solvents for NMR Measurements
- 1H NMR Absorption of Major Chemical Families
- Some Useful 1H Coupling Constants
- Additivity Rules in 13C-NMR Correlation Tables
- 13C-NMR Absorption of Major Functional Groups
- 13C-NMR Chemical Shifts of Organic Families
- 15N Chemical Shifts for Common Standards
- 15N Chemical Shifts of Major Chemical Families
- 15N Spin-Spin Coupling
- 19F Chemical Shift Ranges
- 19F Chemical Shifts of Some Fluorine-Containing Compounds
- 19F Coupling Constants
- Residual Peaks Observed in the 1H NMR Spectra of Common Deuterated Organic Solvents
- Mass Spectroscopy
- Natural Abundance of Important Isotopes
- Rules for Determination of Molecular Formula
- Neutral Moieties Ejected from Substituted Benzene Ring Compounds
- Order of Fragmentation Initiated by the Presence of a Substituent on a Benzene Ring
- Chlorine-Bromine Combination Isotope Intensities
- Reference Compounds Under Electron Impact Conditions in Mass Spectroscopy
- Major Reference Masses in the Spectrum of Heptacosafluorotributylamine
- Common Fragmentation Patterns of Families of Organic Compounds
- Common Fragments Lost
- Important Peaks in the Mass Spectra of Common Solvents
- Reagent Gases for Chemical Ionization Mass Spectrometry
- Proton Affinity of Reactant Gases in Chemical Ionization Mass Spectrometry
- Proton Affinities of Some Simple Molecules
- Proton Affinities of Some Anions
- Detection of Leaks in Mass Spectrometers
- Mass Resolution Required to Resolve Common Spectral Interferences Encountered in Inductively Coupled Plasma Mass Spectrometry (ICP-MS)
- Atomic Absorption Spectrometry
- Introduction for Atomic Spectrometric Tables
- Standard Solutions-Selected Compounds and Procedures
- Limits of Detection for Common Analytical Transitions in AES and AAS Detect
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